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The title "Headmistress" existed at Dio from 1903 to 1993. It was then replaced in 1993 with the title "Principal", and has been used ever since.
There have been 13 headmistresses/principals since Dio opened in 1903.
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Principals
. Diocesan School for Girls Archives, accessed 20/05/2026, https://dio.recollect.co.nz/nodes/view/8